Product ID:CARC-B ACTIVATOR COMP B 4 TO 1 BLEND
MSDS Date:11/15/1991
FSC:8010
NIIN:01-162-5578
Kit Part:Y
MSDS Number: BMXKQ

NILES CHEMICAL PAINT CO

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 219-236-5856

Info Phone: 616-683-3377

Preparer: MIKE LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

1,6-HEXAMETHYLENE DIISOCYANATE (VAPOR PRESSURE 9 MM @ 20 C)

Fraction By Weight: 75%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/100 PPM STEL

HEXAMETHYLENE DIISOCYANATE (RESIDUAL MONOMER CONTENT LESS

CAS: 822-06-0

RTECS: MO1740000

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

# MONTHS STORAGE, FREE MONOMER CONTENT MAY RISE TO 1.6%

RTECS: 9999999ZZ

XYLENE (SARA III) (VAPOR PRESSURE 7.0 MM @ 20 C)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 12%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150 PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BUTYL ACETATE (SARA III) (VAPOR PRESSURE 10 MM @ 20 C)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 12%

OSHA PEL 150 PPM

ACGIH TLV: 150 PPM/200 PPM STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PROPRIETARY INGREDIENTS (MFR STATES UNIDENTIFIED INGREDS

Fraction By Weight: BALANCE

2.15 LBS/GAL

RTECS: 9999999VO

LD50 LC50 Mixture:ORAL LD50: 4,300 MG/KG (RATS) *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: MUCOUS MEMBRANE/RESP TRACT
IRRIT. BRONCHITIS/SPASMS, PULMONARY EDEMA. CHEM/HYPERSENSITIVE
PNEUMONITIS. NOSE/THROAT/EYE IRRIT. IMMED DANGEROUS TO LIFE/HEALTH.
ISOCYANATE SENSITIZATION (CHEM ASTH MA). NON-SPECIFIC ASTHMATIC
RESPONSES. LUNG DAMAGE/REDUCED FUNCTION. PERM BRAIN & NERV SYS
DAMAGE. NEUROTOXIC EFFECTS.**
Explanation of Carcinogenicity:NOT LISTED BY NTP, IARC, OR OSHA.
*INHAL LC50 137 TO 1150 MG/M3 (RATS). MORE
INFO ON FILE.
Effects of Overexposure:INHAL: RUNNY NOSE, SORE THROAT, COUGH, CHEST
DISCOMFORT, SHORT BREATH, BREATH OBSTRUCT. FLU-LIKE SYMPTOM. DRY
THROAT/TIGHT CHEST. HEADACHE, NAUSEA, NARCOSIS, FATIGUE, APPETITE
LOSS. WHEEZE, ASTHMA ATT ACK. INTELLECT/COORDINATN LOSS. SKIN: RED,
SWELL, RASH, SCALING, BLISTER. DRY, CRACKED SKIN. INFECTION
SUSCEPTIBLE.***
Medical Cond Aggravated by Exposure:ASTHMA/RESP DISORDERS (BRONCHITIS,
EMPHYSEMA, HYPER-REACTIVITY) SKIN ALLERGIES, ECZEMA.
***SKIN: IRRIT. SYSTEMIC EFFECT THRU SKIN ABSORPTN. EYE:
IRRIT. INGEST: IRRIT/CORROSIVE****

First Aid:INHAL: MOVE TO FRESH AIR. ADMIN OXYGEN/ARTIF RESP AS NEEDED.
GET MED AID. ASTHMATIC SYMPTOMS MAY DEVELOP, TREAT SYMPTOMS. SEE
DR. SKIN: REMOVE CONTAM CLOTH IMMED. WASH W/SOAP & WTR. WASH CONTAM
CLOTH BEFORE REUSE. SEVERE EXPOS, GET UNDER SFTY SHOWER AFTER
REMOVING CLOTH. GET MED AID. FOR LESSER EXPOS, GET MED AID IF IRRIT
DEVELOPS. EYE: FLUSH W/LUKEWARM WATER (LOW PRESS) 15 MIN, LIFT
EYELIDS.*****

Flash Point Method:SCC
Flash Point:72.0F,22.2C
Lower Limits:1.0
Upper Limits:7.6
Extinguishing Media:DRY CHEMICAL, FOAM, ALCOHOL FOAM, CO2.
Fire Fighting Procedures:FULL EMERGENCY EQUIP W/SCBA & FULL PROTECTIVE
CLOTH. VAPOR HEAVIER THAN AIR, MAY TRAVEL ON GROUND TO IGNITION
SOURCE AND FLASH BACK.
Unusual Fire/Explosion Hazard:HDI VAPOR & OTHER IRRITATING OR HIGHLY
TOXIC GASES GENERATED BY COMBUSTION. CLOSED CONTAINER MAY EXPLOD
W/HEAT OR WHEN CONTAMINATED W/WATER CREATING CO2.

Spill Release Procedures:EVAC NONESSENTIAL. REMOVE IGNIT SOURCES. VENT
AREA. DIKE. NOTIFY AUTHORITIES. COVER W/SAWDUST, VERMIC, FULLER'S
EARTH, ETC. POUR DECONTAM SOLUTION OVER SPILL, ALLOW TO REACT 10
MIN. COLLECT IN OPEN CN TNRS, COVER LOOSELY. LET STAND 24-48 HRS.
Neutralizing Agent:TERGITOL TMN-10 (20%)/WATER (80%); CONC AMMONIA
(3-8%)/DETERG (2%)/WTR (90-95%)

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, OPEN
FLAME. GRND CNTNRS DURING STORAGE & TRANSFER OPERATIONS. STORE IN
TIGHTLY CLSD CNTNRS TO PREVENT MOISTURE CONTAM.
Other Precautions:DO NOT RESEAL IF CONTAM SUSPECTED. AT MAX STORAGE
TEMPERATURES NOTED, MAT'L MAY SLOWLY POLYMERIZE WITHOUT HAZARD.
IDEAL STORAGE TEMPERATURE RANGE 50-80F. AVOID CONTACT W/SKIN &
EYES. EMPLOYEE EDUCATIO N/TRAIN IN SAFE USE/HANDLING REQUIRED.

Respiratory Protection:RSPRTR RECOMMENDED/APPROVED FOR USE IN
ISOCYANATE CONTAINING ENVIRONMENTS (AIR PURIFYING/FRESH AIR
SUPPLIED) MAY BE NECESSARY. CONSIDER TYPE OF APPLICATION &
ENVIRONMNTL CONC. OBSERVE OSHA REGULATIONS FOR RESPIRATOR USE (29
CFR 1910.134).
Ventilation:PROVIDE EXHAUST VENT SUFF TO KEEP AIRBORNE CONC OF HDI &
POLYISOCYANATE BELOW TLV/MGL. SCRUB/FILTER EXHAUST AIR.
Protective Gloves:CHEM RESISTANT GLOVES (NITRILE, VITON)
Eye Protection:SFTY GLASSES, SPLASH GOGGLES, FACE SHLD
Other Protective Equipment:COVER EXPOSED SKIN W/CLOTHING (NITRILE,
VITON). IF SKIN CREAMS USED, KEEP AREA PROTECTED BY ONLY CREAM TO
MINIMUM.
Work Hygienic Practices:DON'T BREATH VAPOR. AVOID CONTACT W/EYES/SKIN.
IN SPRAY OPERATIONS, PROTECT AGAINST EXPOSURE TO VAPOR/MIST.
Supplemental Safety and Health
***EYES: TEAR/RED/SWELLING W/STING. ****ACTION
IN DIGESTIVE TRACT. VOMITING MAY CAUSE ASPIRATION OF SOLVENT
RESULTING IN CHEM PNEUMONITIS. *****GET TO
DR/OPTHM ALOGIST IMMED. INGEST: DON'T INDUCE VOMIT. DRINK 1-2 CUPS
MILK/WATER. NOTHING BY MOUTH TO UNCONSCIOUS/CONVULSING PERSON.

Boiling Pt:B.P. Text:250 TO 289F
Vapor Density:> AIR
Spec Gravity:8.85 LBS/GAL
Viscosity:183 MPAS
Evaporation Rate & Reference:SLOWER THAN ETHER.
Solubility in Water:INSOLUBL/REACT W/WTR
Appearance and Odor:CLEAR TO PALE YELLOW LIQUID; SOLVENT ODOR.
Percent Volatiles by Volume:30.31

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, NITRATES, ALKALIES, ACIDS.
Stability Condition to Avoid:MOISTURE, HIGH TEMPERATURES, SHOCK FROM
DROPPING.
Hazardous Decomposition Products:BY HIGH HEAT AND FIRE: CARBON DIOXIDE,
CARBON MONOXIDE, OXIDES OF NITROGEN, TRACES OF HCN & HDI.
Conditions to Avoid Polymerization:MAY OCCUR IF IN CONTACT WITH
MOISTURE OR OTHER MATERIALS WHICH REACT WITH ISOCYANATES. MAY OCCUR
AT TEMPERATURES >400F.

Waste Disposal Methods:WASTE MUST BE DISPOSE OF IN ACCORDANCE W/FED,
STATE, LOCAL REGS. INCINERATION PREFERRED. EMPTY CNTNR MUST BE
HANDLED W/CARE. DECONTAM CNTNRS PRIOR TO DISPOSAL. DON'T HEAT/CUT
ON/NEAR EMPTY CNTNRS W/EL ECTRICAL OR GAS TORCH.
RCRA--IGNITIBLE;D001.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.